Application of native plants in constructed floating wetlands as a passive remediation approach for PFAS-impacted surface water.

Strategies for remediation of per- and polyfluoroalkyl substances (PFAS) generally prioritise highly contaminated source areas. However, the mobility of PFAS in the environment often results in extensive low-level contamination of surface waters across broad areas. Constructed Floating Wetlands (CFWs) promote the growth of plants in buoyant structures where pollutants are assimilated into plant biomass. This study examined the hydroponic growth of Juncus krausii, Baumea articulata and Phragmites australis over a 28-day period for remediation of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) contaminated (0.2 µg/L to 30 µg/L) urban stormwater. With increasing PFOA and PFOS concentrations, accumulation in plant species increased although root and shoot distribution varied depending on PFAS functional group. Less PFOA than PFOS accumulated in plant roots (0.006-0.16 versus 0.008-0.68 µg/g), while more PFOA accumulated in the plant shoots (0.02-0.55 versus 0.01-0.16 µg/g) indicating translocation to upper plant portions. Phragmites australis accumulated the highest overall plant tissue concentrations of PFOA and PFOS. The NanoSIMS data demonstrated that PFAS associated with roots and shoots was absorbed and not just surface bound. These results illustrate that CFWs have the potential to be used to reduce PFAS contaminants in surface waters.

The influence of evaporation from porous concrete on air temperature and humidity.

Porous concrete is increasingly being used as a more sustainable surfacing alternative to asphalt and other impermeable materials. This is because, not only does it provide source control of stormwater, but it also has the potential to help mitigate the urban heat island effect through the process of evaporative cooling. This experimental investigation examines how evaporation from these systems is affected by the availability of water within the porous concrete and the influence this has on the surrounding environment, particularly in terms of air temperature and humidity. The effect of a dual layer porous concrete on evaporation rates is also assessed, which is important because the dual layer system is a relatively new development that is now being used in many parts of the world. It was found that both evaporation rate and evaporative cooling were strongly influenced by water availability near the upper surface of the porous concrete and under these conditions significant air temperature reductions can be achieved. It was also found that having a dual layered porous concrete system did not have a considerable effect on evaporation rates in this study, probably because of the relatively large thickness of the upper layer.

The influence of rainfall intensity and duration on sediment pathways and subsequent clogging in permeable pavements.

The trapping of sediments within permeable pavements during infiltration is an important process that contributes to their water quality treatment performance. However, this process also leads to clogging, which decreases the infiltration capacity of the pavement. With different rainfall intensities and durations, this study investigates the amount and size of sediment passing through a porous paver, as well as through the gravel-filled gaps that separate adjacent pavers. One of the major challenges in this study was to design an experiment where the characteristics of the sediment particles that are trapped while passing through these two different infiltration pathways are assessed. This was overcome by developing a new type of rainfall application device in combination with a two-tiered sediment capturing system. A better understanding of the infiltration pathways of sediment and the associated clogging processes should help designers improve the effective life of permeable pavements. Overall, it was found that while the porosity of porous pavers serves a useful function in terms of removing excess surface water during and after a rainfall event, it serves little purpose in removing sediment from stormwater.

A field and laboratory investigation of kerb side inlet pits using four media types.

Kerb side inlets with adjacent leaky wells are an emerging tool to harvest stormwater and to reduce runoff volumes and peak flow rates. This is achieved by collecting the first flush runoff into kerb side storages and infiltrating this water into the surrounding soil, thereby also reducing stormwater pollutant loadings. The hydraulic performance of the kerb side inlet, filter media and surrounding soil are key factors in the performance of these systems. However, no field or laboratory data are currently available for the hydraulic performance of a kerb side tree inlet pit. In this study, 12 tree inlet pits were constructed and filled with various media types including gravel, water treatment solids (a recycled waste product), sandy loam and clay to examine (1) leaky well infiltration rates (2) emptying times of the wells and (3) the well capacity (runoff storage volume) before and after runoff filtering through the wells. Using a laboratory model, the water harvesting performance of the kerb side inlet plate was also examined for various road longitudinal slopes. Using the field and laboratory data, simulation of the well performance was undertaken using the Model for Urban Stormwater Improvement Conceptualisation (MUSIC) to assess the capacity of these systems to reduce runoff volumes at the residential street scale. It was hypothesised that the type of filter media used in leaky well systems has a significant impact on the infiltration rate, regardless of the native soil type through which the stormwater eventually infiltrates. The results showed that the infiltration rates of systems filled with gravel were significantly higher than for the other media types, and this was followed by water treatment solids, sandy loam and clay. The results of the MUSIC modelling indicated that 2.8% of the mean annual runoff volume in the catchment could be harvested by the systems at the case study site. It was found that selection of high infiltration rate media and regular maintenance are the key factors for maintaining long-term performance of these systems.

Transformation pathway and toxicity assessment of malathion in aqueous solution during UV photolysis and photocatalysis.

In drinking water treatment, complete mineralization of organophosphorus pesticides (OPPs) by UV-based advanced oxidation processes (UV AOPs) is rarely achieved. The formation of intermediate oxidation byproducts would likely have some profound effects on toxicity of the reaction solutions. This study investigated the intermediate oxidation byproducts, transformation pathway and toxicity of malathion solutions during the treatment processes of UV alone, UV/H2O2, UV/TiO2 and UV/Fenton. The main intermediate oxidation byproducts were derived using ultra-performance liquid chromatography - electrospray - time-of-flight mass spectrometry. Thereby the transformation pathway for each of these treatment processes was proposed. The results indicate that in UV photolysis, the transformation pathway of malathion proceeded initially via cleavage of the phosphorus-sulfur bonds while in photocatalysis, the desulfurization from a PS bond to a PO bond was the primary degradation pathway. Interestingly, only in the UV/TiO2 process a small fraction of malathion was found decomposed via a demethylation reaction. At the same time, a toxicity assessment of the treated solutions was conducted by both luminescence inhibition of Vibrio fischeri and inhibition of acetylcholinesterase (AChE). It was found that after UV AOP treatment, the toxicity of the malathion aqueous solution increased sharply. In contrast, no increase in toxicity was observed for the malathion aqueous solution after UV alone treatment. This study demonstrates that the high removal efficiency achieved by OPPs does not imply that detoxification of the water solution has been achieved. On the contrary, the toxicity of the treated solutions by OPPs may be increased significantly depending on the selected treatment processes.

Development of a non-stationary Standardized Precipitation Index and its application to a South Australian climate.

In a changing climate, while hydroclimatic variables such as precipitation may show non-stationary behaviour, a traditional Standardized Precipitation Index (SPI) is not capable of accurately predicting extreme meteorological droughts. In this study, we have developed a non-stationary Standardized Precipitation Index (NSPI) within the Generalized Additive Model in Location, Scale and Shape (GAMLSS) modelling framework. This incorporates various climate indices such as SOI, Niño3.4, PDO, SAM and DMI as external covariates to capture the non-stationary and nonlinear characteristics of precipitation and thereby droughts. This idea has been applied at 46 high quality rainfall stations in the state of South Australia. The results indicate that a non-stationary model that considers climate indices can reproduce the rainfall variability better than a stationary model thereby NSPI is better than a traditional stationary SPI (SSPI) at capturing drought characteristics. Bivariate frequency analysis shows that the recurrence interval of drought events exceeding any severity and duration of interest is significantly different for NSPI compared to SSPI. This study demonstrates the need to use a non-stationary drought index in a changing climate to accurately represent the drought characteristics.

Performance of a kerb side inlet to irrigate street trees and to improve road runoff water quality: a comparison of four media types.

The TREENET inlet is an emerging water-sensitive urban design technology that consists of a novel kerb side inlet coupled with a leaky well infiltration system. The inlets have been retrofitted to existing roads since 2006; however, there is currently little information available on the effectiveness of these inlet and leaky well systems. This study investigated the performance of the kerb side inlets and leaky well system for water quality improvement prior to infiltration to native soil. The leaky wells included four filter media types, namely gravel, water treatment solids, sandy loam and clay. To compare the performance of the four filter media types, batch and column studies were performed in the laboratory. The best performance was observed using the sandy loam as a filter media, followed by clay, water treatment solids and then gravel. The selection of effective media for removal of heavy metals is important as each media type has different pollutant removal capacity, infiltration and clogging performance.

NDVI, scale invariance and the modifiable areal unit problem: An assessment of vegetation in the Adelaide Parklands.

This research addresses the question as to whether or not the Normalised Difference Vegetation Index (NDVI) is scale invariant (i.e. constant over spatial aggregation) for pure pixels of urban vegetation. It has been long recognized that there are issues related to the modifiable areal unit problem (MAUP) pertaining to indices such as NDVI and images at varying spatial resolutions. These issues are relevant to using NDVI values in spatial analyses. We compare two different methods of calculation of a mean NDVI: 1) using pixel values of NDVI within feature/object boundaries and 2) first calculating the mean red and mean near-infrared across all feature pixels and then calculating NDVI. We explore the nature and magnitude of these differences for images taken from two sensors, a 1.24m resolution WorldView-3 and a 0.1m resolution digital aerial image. We apply these methods over an urban park located in the Adelaide Parklands of South Australia. We demonstrate that the MAUP is not an issue for calculation of NDVI within a sensor for pure urban vegetation pixels. This may prove useful for future rule-based monitoring of the ecosystem functioning of green infrastructure.

Remediation of metalliferous mines, revegetation challenges and emerging prospects in semi-arid and arid conditions.

Understanding plant behaviour in polluted soils is critical for the sustainable remediation of metal-polluted sites including abandoned mines. Post-operational and abandoned metal mines particularly in semi-arid and arid zones are one of the major sources of pollution by soil erosion or plant hyperaccumulation bringing ecological impacts. We have selected from the literature 157 species belonging to 50 families to present a global overview of 'plants under action' against heavy metal pollution. Generally, all species of plants that are drought, salt and metal tolerant are candidates of interest to deal with harsh environmental conditions, particularly at semi-arid and arid mine sites. Pioneer metallophytes namely Atriplex nummularia, Atriplex semibaccata, Salsola kali, Phragmites australis and Medicago sativa, representing the taxonomic orders Caryophyllales, Poales and Fabales are evaluated in terms of phytoremediation in this review. Phytoremediation processes, microbial and algal bioremediation, the use and implication of tissue culture and biotechnology are critically examined. Overall, an integration of available remediation plant-based technologies, referred to here as 'integrated remediation technology,' is proposed to be one of the possible ways ahead to effectively address problems of toxic heavy metal pollution. Graphical abstract Integrated remediation technology (IRT) in metal-contaminated semi-arid and arid conditions. The hexagonal red line represents an IRT concept based on remediation decisions by combination of plants and microbial processes.

Insight into dissolved organic matter fractions in Lake Wivenhoe during and after a major flood.

Dissolved organic matter is an important component of biogeochemical processes in aquatic environments. Dissolved organic matter may consist of a myriad of different fractions and resultant processing pathways. In early January 2011, heavy rainfall occurred across South East Queensland, Australia causing significant catchment inflow into Lake Wivenhoe, which is the largest water supply reservoir for the city of Brisbane, Australia. The horizontal and vertical distributions of dissolved organic matter fractions in the lake during the flood period were investigated and then compared with stratified conditions with no catchment inflows. The results clearly demonstrate a large variation in dissolved organic matter fractions associated with inflow conditions compared with stratified conditions. During inflows, dissolved organic matter concentrations in the reservoir were fivefold lower than during stratified conditions. Within the dissolved organic matter fractions during inflow, the hydrophobic and humic acid fractions were almost half those recorded during the stratified period whilst low molecular weight neutrals were higher during the flood period compared to during the stratified period. Information on dissolved organic matter and the spatial and vertical variations in its constituents' concentrations across the lake can be very useful for catchment and lake management and for selecting appropriate water treatment processes.

Aqueous arsenite removal by simultaneous ultraviolet photocatalytic oxidation-coagulation of titanium sulfate.

This study explored the efficacy and efficiency of a simultaneous UV-catalyzed oxidation-coagulation process of titanium sulfate (UV/Ti(SO4)2) for efficient removal of As(III) from water. It revealed that, As(III) could be oxidized to As(V) during the UV catalyzed coagulation of Ti(SO4)2 with highly efficient As(III) removal in the pH range 4-6. The UV catalyzed oxidation-coagulation showed surprisingly effective oxidation of As(III) to As(V) within a short time. XPS indicated that 84.7% of arsenic on the coagulated precipitate was in the oxidized form of As(V) after the UV/Ti(SO4)2 treatment of As(III) aqueous solutions at pH 5. Arsenic remaining in solution at high pH was in the oxidized form As(V). Removal efficiencies of As(III) were investigated as a function of pH, Ti(SO4)2 dosage, initial As(III) concentration and irradiation energy. As(III) could almost completely be removed (>99%) by the photocatalytic oxidation-coagulation process with a moderate dose of Ti(SO4)2 in the pH range 4-6 at an initial arsenic concentration of 200 µg/L. The mechanisms of the photocatalytic coagulation oxidation of Ti(SO4)2 are similar to those of UV/crystalline TiO2 particles, involving the formation and reactions of the hydroxyl radical OH and superoxide HO2/O2(-).

Impact of elemental uptake in the root chemistry of wetland plants.

Plants play a key role in the accumulation of metals in contaminated environment. Ephemeral plants, such as cyperus vaginatus, from the family Cyperaceae have been used in constructed wetlands to alter the biogeochemistry of waterlogged soils. High elemental content in wetlands often induces chemical changes in the root, stem and leaf of wetland plants. Elemental uptake and possible chemical changes in the roots of Cyperus vaginatus was investigated and compared with plants grown away from the wetland. Among the 9 heavy metals (Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb) and metalloid (As) measured, with the exception of Mn, all metals had higher content in the plant roots grown within the wetland. This was followed by plants grown near to the wetland that receive stormwater occasionally and then plants grown far from the wetland. The 3-D fluorescence spectra record showed notable differences in the chemical composition of roots grown in the three locations. The spectra combined with parallel factor analysis showed three dominant fluorescence components. Comparison of the fluorescence signatures showed a continuum of spectral properties constrained by the degree of metal contamination.

Statistical downscaling of CMIP5 outputs for projecting future changes in rainfall in the Onkaparinga catchment.

A generalized linear model was fitted to stochastically downscaled multi-site daily rainfall projections from CMIP5 General Circulation Models (GCMs) for the Onkaparinga catchment in South Australia to assess future changes to hydrologically relevant metrics. For this purpose three GCMs, two multi-model ensembles (one by averaging the predictors of GCMs and the other by regressing the predictors of GCMs against reanalysis datasets) and two scenarios (RCP4.5 and RCP8.5) were considered. The downscaling model was able to reasonably reproduce the observed historical rainfall statistics when the model was driven by NCEP reanalysis datasets. Significant bias was observed in the rainfall when downscaled from historical outputs of GCMs. Bias was corrected using the Frequency Adapted Quantile Mapping technique. Future changes in rainfall were computed from the bias corrected downscaled rainfall forced by GCM outputs for the period 2041-2060 and these were then compared to the base period 1961-2000. The results show that annual and seasonal rainfalls are likely to significantly decrease for all models and scenarios in the future. The number of dry days and maximum consecutive dry days will increase whereas the number of wet days and maximum consecutive wet days will decrease. Future changes of daily rainfall occurrence sequences combined with a reduction in rainfall amounts will lead to a drier catchment, thereby reducing the runoff potential. Because this is a catchment that is a significant source of Adelaide's water supply, irrigation water and water for maintaining environmental flows, an effective climate change adaptation strategy is needed in order to face future potential water shortages.

Heavy metal pollution and health risk assessment in the Wei River in China.

From data collected monthly at 26 monitoring cross sections in the Wei River in the Shaanxi Region of China during the period 2008-2012, the temporal pollution characteristics of heavy metals (Hg, Cd, Cr(VI), Pb, and As) were analyzed based on a heavy metal pollution index (HPI). The monthly HPI values of the five heavy metals in the river fluctuated greatly in 2008 and then declined gradually with time. This general trend of reduction in HPI appears not to have a seasonal variation and most likely resulted from the continued improvement in heavy metal pollution control strategies implemented by local environmental agencies combined with a significant improvement in wastewater treatment capacities. Among the five heavy metals, Cd and Pb were below 0.1 and 3 µg L(-1), respectively, at all the sampling points in the studied areas in the year 2012. The detection rates of As, Hg, and Cr(VI) were in the order of Hg > Cr(VI) > As. Hg, Cr(VI), and As exceeded, in a month of the dry season in 2012, the standard limits for category III surface waters according to the China Environment Quality Standards for Surface Water (CEQSSW). Based on the assessment using the HPI method, the pollution status of these heavy metals in water of the Wei River in the Shaanxi Region was generally at an acceptable level, but exhibited distinctive characteristics between the main stream river and tributaries. Most of the tributaries were more seriously polluted than the main river. A health risk assessment was conducted based on the Human Health Risk Assessment (HHRA) method recommended by the United States Environmental Protection Agency (USEPA). Apart from As, the health risk for the five heavy metals in the region were at acceptable levels for drinking water sources (hazard quotient (HQ) < 1, carcinogenic risk (CR) ranged from 10(-4)-10(-6)) according to the Risk Assessment Guidance for Superfund (RAGS), USEPA. Arsenic was identified as the most important pollutant of concern among the five heavy metals; both its values of the HQ and CR indicated potentially adverse health risks for the local population.

Variation in PAH patterns in road runoff.

Twelve particle-bound polycyclic aromatic hydrocarbons (PAHs) were measured in the first flush regime of road runoff during nine events in Winterthur in Switzerland. The total PAH contents ranged from 17 to 62 µg/g. The PAH patterns measured at different time intervals during the first flush periods were very similar within each event irrespective of variation in suspended solids (SS) concentration within the first flush regime. However, the PAH patterns were different from event to event. This indicates that the environment plays an important role in PAH accumulation in SS. A toxicity identification evaluation approach using a toxicity equivalency factor (TEF) was applied to compare toxicities in the different events. The TEFs were found to be between 8 and 33 µg TEQ g(-1) (TEQ: toxic equivalent concentration). In some cases, two events having similar total PAH contents showed two fold toxicity differences.